Rate of Reaction and Equilibrium | AQA GCSE Chemistry | Topic 6

  • Mean rate of reaction = amount of reactant used/ time taken = amount of product formed/ time taken.
  • Rate of reaction can be measured in g/s or cm3/s etc.
  • Rate of reaction is fastest at the start and then slows down.
  • Exact rate of reaction: draw a tangent and work out gradient.
  • Gradient = rise/ run between two points.
  • Rate of reaction is fastest at the start and slowest at the end.
  • Factors affecting rate of reaction: concentration, pressure, surface area of the reactants, temperature, catalysts.
  • Apart from catalysts, they make particles closer together and increase frequency of collisions,
  • Catalysts: provide an alternative reaction pathway with a lower activation energy, without being used up.
  • Activation energy: minimum energy needed to start a reaction successfully.
energy profiles
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  • Reversible Reactions: when the products of the reaction can react to produce the original reactants
  • Closed system: nothing can enter or leave the reactants
  • Equilibrium: in a closed system, when the rate of forward reaction equals the rate of backward reaction
  • Le Chatelier's Principle: when a condition is changed, equilibrium moves to oppose the change.
  • Higher temperature: equilibrium moves to the endothermic side
  • Lower temperature: equilibrium moves to the exothermic side
  • Higher concentration of reactants: equilibrium moves to the right
  • Lower concentration of reactants: equilibrium moves to the left
  • Higher concentration of products: equilibrium moves to the left
  • Lower concentration of products: equilibrium moves to the right
  • Higher pressure: equilibrium moves to the side with less moles of gas (count big numbers and count gas only).
  • Lower pressure: equilibrium moves to the side with more moles of gas